In a sample of a substance, the particles (atoms or molecules) have a distribution of energies at any given temperature. This is known as the Maxwell-Boltzmann distribution.
According to this distribution, some particles have high energies, while others have low energies, but the average energy of the particles is constant at a given temperature.
The energy of individual particles in a sample is not the same, as they are in constant motion and colliding with each other, leading to a range of energies.
This is why the concept of average energy or kinetic energy is used to describe the energy of a sample as a whole.
The subject of the sentence is "Twenty five kilometers", which is a singular noun phrase, so the verb should be singular as well. The correct verb would be "is", not "are".
The corrected sentence would be: "Twenty five kilometers from Hala to Hyderabad is a long distance."